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5: Tools of the Trade . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 6: Your Electronic Parts Supply . . . . . . . . . . . . . . . . . . . . . . . . . . 47 7: The Well-Behaved Workspace . . . . . . . . . . . . . . . . . . . . . . . . . 75

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Polymers are macromolecules built up by the linking together of large numbers of much smaller molecules. The small molecules that combine with each other to form polymer molecules are termed monomers, and the reactions by which they combine are termed polymerizations. There may be hundreds, thousands, tens of thousands, or more monomer molecules linked together in a polymer molecule. When one speaks of polymers, one is concerned with materials whose molecular wights may reach into the hundreds of thousands or millions.

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1-1 TYPES OF POLYMERS AND POLYMERIZATIONS There has been and still is considerable confusion concerning the classi cation of polymers. This is especially the case for the beginning student who must appreciate that there is no single generally accepted classi cation that is unambiguous. During the development of polymer science, two types of classi cations have come into use. One classi cation is based on polymer structure and divides polymers into condensation and addition polymers. The other classi cation is based on polymerization mechanism and divides polymerizations into step and chain polymerizations. Confusion arises because the two classi cations are often used interchangeably without careful thought. The terms condensation and step are often used synonymously, as are the terms addition and chain. Although these terms may often be used synonymously because most condensation polymers are produced by step polymerizations and most addition polymers are produced by chain polymerizations, this is not always the case. The condensation addition classi cation is based on the composition or structure of polymers. The step chain classi cation is based on the mechanisms of the polymerization processes.

Principles of Polymerization, Fourth Edition. By George Odian ISBN 0-471-27400-3 Copyright # 2004 John Wiley & Sons, Inc.

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Polymers were originally classi ed by Carothers [1929] into condensation and addition polymers on the basis of the compositional difference between the polymer and the monomer(s) from which it was synthesized. Condensation polymers were those polymers that were formed from polyfunctional monomers by the various condensation reactions of organic chemistry with the elimination of some small molecule such as water. An example of such a condensation polymer is the polyamides formed from diamines and diacids with the elimination of water according to

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8: Soldering Your Way to Nirvana . . . . . . . . . . . . . . . . . . . . . . . . . 85 9: Designing Your Personal Alien Orchestra . . . . . . . . . . . . . . . . . . . 103 10: Building the Bent Instrument . . . . . . . . . . . . . . . . . . . . . . . . 131 11: Bending Beyond the Basics . . . . . . . . . . . . . . . . . . . . . . . . . . 149 12: Finishing Techniques . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175

where R and R0 are aliphatic or aromatic groupings. The unit in parentheses in the polyamide formula repeats itself many times in the polymer chain and its termed the repeating unit. The elemental composition of the repeating unit differs from that of the two monomers by the elements of water. The polyamide synthesized from hexamethylene diamine, R CH2 6 , and adipic acid, R0 CH2 4 , is the extensively used ber and plastic known commonly as nylon 6/6 or poly(hexamethylene adipamide). Other examples of condensation polymers are the polyesters formed from diacids and diols with the elimination of water and the

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polycarbonates from the reaction of an aromatic dihydroxy reactant and phosgene with the elimination of hydrogen chloride:

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